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Preheat the oven to 250°F. Line a baking sheet with parchment paper. Combine butter, syrup, 2 tablespoons water, salt, cinnamon and chili powder in a large saucepan. Bring to a boil, stirring constantly. Mix in walnuts and stir to evenly coat. Spread nuts in a single layer on baking sheet. Sprinkle with turbinado sugar. Bake 45 minutes to an hour, stirring every 15 minutes. Spread on waxed or parchment paper to cool. Store in an airtight container or package for gift giving.